Brad and Angelina Top 10 Red Carpet Moments

Actress Angelina Jolie and actor Brad Pitt arriving at the 23rd Annual Producers' Guild Awards at The Beverly Hilton hotel on January 21, 2012 in Beverly Hills, California. Philip Vaughan

4) The actress’s infamous leg poses at the 2012 Academy Awards overshadowed her gown but despite the controversy, Angelina looked amazing in the black velvet Atelier Versace dress. Her envied pout was accentuated with red lipstick. Pitt accompanied his now-fiance dressed in a traditional Tom Ford tux.

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