10. Brad Pitt and Angelina Jolie
Before becoming Brangelina, Pitt and Jolie met while filming their sexy spy movie Mr. and Mrs. Smith in 2005.
Since then, the couple has become one big, happy family. They have six children together: Maddox, 13, Pax, 11, Zahara, 10, Shiloh, 9, and twins Vivienne and Knox, 7. They tied the knot in 2014 in an intimate ceremony with just their family present.
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