7. Chef
Even though he, and his voice actor Isaac Hayes, have passed, the character of Chef once served as the most relied-on adult character on the show, and for good reason. Inspired by both 70s soul singers, including Hayes, and a cafeteria cook in Parker's University of Colorado, Chef used to be the one that would help—and fail—to let the boys in on the mysteries of the outside, adult world, and would always be quick to sing a song or persuade a lovely lady to make love to him.
While his final days were perhaps not as nice as many— including Parker and Stone, would have likely hoped—he still remains one of the funniest and most charming characters in South Park history.
Speaking of songs, here is, in my opinion, his best. This is also probably the best or second best song about prostitutes in TV history. It's between this and the one from Flight of the Conchords:
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